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[C(NH2)3]2MoO2F4·H2O: Unique Chinese-Knot Structure Revealing Superior Nonlinear-Optical Properties
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2022-09-07 , DOI: 10.1021/acs.inorgchem.2c02861
Wei Zeng 1 , Yao Tian 1 , Ling Huang 2 , Hongmei Zeng 1 , Zhien Lin 1 , Guohong Zou 1
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A novel organic–inorganic hybrid guanidine fluoromolybdate, [C(NH2)3]2MoO2F4·H2O, was successfully synthesized via our proposed cation–anion synergetic interaction strategy. The title compound features a unique Chinese-knot structure constructed by hydrogen-bonding interactions, which induces an all-around improvement of the optical band gap, second-harmonic-generation effect, and phase-matchable ability compared with the reported fluoromolybdates, demonstrating that it is a promising UV nonlinear-optical material.
更新日期:2022-09-07
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