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Palladium Complexes [Ph3PEt][PdBr3(DMSO)], [Ph3PCH2OMe][PdBr3(DMSO)], [Ph3PC5H9-cyclo][PdBr3(DMSO)], and [Ph3PCH2CH=CHCH2PPh3][PdBr3(DMSO)]2: Synthesis and Structure
Russian Journal of Coordination Chemistry ( IF 1.1 ) Pub Date : 2022-09-07 , DOI: 10.1134/s1070328422090044
V. V. Sharutin , O. K. Sharutina , V. S. Senchurin
更新日期:2022-09-07
Russian Journal of Coordination Chemistry ( IF 1.1 ) Pub Date : 2022-09-07 , DOI: 10.1134/s1070328422090044
V. V. Sharutin , O. K. Sharutina , V. S. Senchurin
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Abstract
Ionic complexes of palladium(II) with mononuclear anions [Ph3PEt][PdBr3(DMSO)] (I), [Ph3PCH2OMe][PdBr3(DMSO)] (II), [Ph3PC5H9-cyclo][PdBr3(DMSO)] (III), and [Ph3PCH2CH= CHCH2PPh3][PdBr3(DMSO)]2 (IV) are synthesized from organyl triphenylphosphonium bromide and palladium(II) bromide in the presence of hydrobromic acid. The structures of the complexes are determined by X-ray diffraction (CIF files CCDC nos. 2115506 (I), 2115228 (II), 888748 (III), and 2115007 (IV)). The complexes contain organyltriphenylphosphonium cations and [PdBr3(DMSO)] anions.