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Resonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study by Reaction Calorimetry
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2010-12-29 , DOI: 10.1021/ja109596m Patrick G. Campbell 1 , Eric R. Abbey 1 , Doinita Neiner 1 , Daniel J. Grant 1 , David A. Dixon 1 , Shih-Yuan Liu 1
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2010-12-29 , DOI: 10.1021/ja109596m Patrick G. Campbell 1 , Eric R. Abbey 1 , Doinita Neiner 1 , Daniel J. Grant 1 , David A. Dixon 1 , Shih-Yuan Liu 1
Affiliation
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Aromatic and single-olefin six-membered BN heterocycles were synthesized, and the heats of hydrogenation were measured calorimetrically. A comparison of the hydrogenation enthalpies of these compounds revealed that 1,2-azaborines have a resonance stabilization energy of 16.6 ± 1.3 kcal/mol, in good agreement with calculated values.
中文翻译：
1,2-氮杂硼的共振稳定能：反应量热法的定量实验研究
合成了芳香族和单烯烃六元 BN 杂环，并通过量热法测量了氢化热。这些化合物的氢化焓的比较表明，1,2-氮杂硼烷的共振稳定能量为 16.6 ± 1.3 kcal/mol，与计算值非常吻合。
更新日期：2010-12-29
中文翻译：
1,2-氮杂硼的共振稳定能：反应量热法的定量实验研究
合成了芳香族和单烯烃六元 BN 杂环，并通过量热法测量了氢化热。这些化合物的氢化焓的比较表明，1,2-氮杂硼烷的共振稳定能量为 16.6 ± 1.3 kcal/mol，与计算值非常吻合。
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