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Diatomic Pd−Cu Metal-Phosphorus Sites for Complete N≡N Bond Formation in Photoelectrochemical Nitrate Reduction
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-08-31 , DOI: 10.1002/anie.202211373
Jie Sun 1 , Hanxue Yang 2 , Weiqi Gao 1 , Tongcheng Cao 1 , Guohua Zhao 1
Affiliation  

An in situ photoreduction strategy is taken to synthesize diatomic Pd−Cu catalysts on 2D phosphorene. Owing to the strength of the unique synergistic effect of PdCuP4 coordination, the adsorption of NO3, the transfer of intermediates, and the formation of N≡N bond are all enhanced, leading to a high NO3 removal rate and N2 selectivity.

中文翻译:

双原子 Pd-Cu 金属-磷位点在光电化学硝酸盐还原中完全形成 N≡N 键

采用原位光还原策略在二维磷烯上合成双原子 Pd-Cu 催化剂。由于PdCuP 4配位的独特协同效应的强度,NO 3 -的吸附、中间体的转移和N≡N键的形成都得到了增强,从而导致较高的NO 3 -去除率和N 2选择性。
更新日期:2022-08-31
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