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Construction of nanoporous Mo2C shell/MoO3 core composite by converting MoO3 and its superior performance in lithium sulfur battery
Journal of Electroanalytical Chemistry ( IF 4.1 ) Pub Date : 2022-08-28 , DOI: 10.1016/j.jelechem.2022.116742
Chongjun Zhao , Sijia Xu , Xu Zhang , Yixuan Wang , Pengfei Rui , Jiexin Zheng , Chunhua Zhao

The lithium-sulfur (Li-S) battery is a promising energy storage device in the future. However, its performance is strongly affected by the shuttle effect and inherent sluggish kinetics. Herein, Mo2C/MoO3-modified separator is constructed, in which MoO3 particles are derived by the decomposition of Mo source and simultaneously their surfaces are converted (reduced and carbonized) into Mo2C, i.e., Mo2C shell/MoO3 core. In addition, the resin matrix of the waste CFRP (Carbon fiber reinforced polymer) acts as the carbon source for the change from MoO3 to Mo2C, while CF is claimed from CFRP. The synergistic effect of conductive Mo2C-shell and polar MoO3-core anchors lithium polysulfide to promote the conversion of sulfur. Benefited from block effect on the soluble lithium polysulfide (LiPS) and catalytic effect on sulfur, Li-S battery with Mo2C/MoO3-modified separator owns excellent electrochemical performance: A high initial discharge specific capacity of 1288 mAh g−1 at 0.2C and an initial capacity of 670 mAh g−1 at 4C, as well as the average decay rate per cycle of 0.039% over 250 times.



中文翻译:

转化MoO3构建纳米多孔Mo2C壳/MoO3核复合材料及其在锂硫电池中的优越性能

锂硫(Li-S)电池是未来很有前途的储能装置。然而,它的性能受到穿梭效应和固有的缓慢动力学的强烈影响。在此,构建了Mo 2 C/MoO 3改性隔膜,其中MoO 3颗粒通过Mo源分解衍生,同时其表面转化(还原和碳化)为Mo 2 C,即Mo 2 C壳/ MoO 3核心。此外,废CFRP(碳纤维增强聚合物)的树脂基体作为MoO 3向Mo 2 C转变的碳源,而CF则从CFRP获得保护。导电钼的协同作用2 C 壳和极性 MoO 3核锚定多硫化锂以促进硫的转化。得益于对可溶性多硫化锂 (LiPS) 的阻断效应和对硫的催化作用,采用 Mo 2 C/MoO 3改性隔膜的 Li-S 电池具有优异的电化学性能:在初始放电比容量高达 1288 mAh g -1 0.2C 和 670 mAh g -1在 4C的初始容量,以及每循环 0.039% 的平均衰减率超过 250 次。

更新日期:2022-08-31
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