One-Pot Structure-Controlled Synthesis of Hyperbranched Polymers by a “Latent” Inimer Strategy Based on Diels–Alder Chemistry,Angewandte Chemie International Edition

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One-Pot Structure-Controlled Synthesis of Hyperbranched Polymers by a “Latent” Inimer Strategy Based on Diels–Alder Chemistry
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-08-18 , DOI: 10.1002/anie.202211713
Neng Yang ₁ , Yu Jiang ₁ , Qinwen Tan ₁ , Jiahui Ma ₁ , Dezhi Zhan ₁ , Zhaohong Wang ₁ , Xin Wang ₂ , Daohong Zhang ₁ , Nikos Hadjichristidis ₂

Affiliation

A “one-pot” strategy for the structure-controlled synthesis of hyperbranched polymers based on a “latent” inimer, containing both a furan-protected maleimide (FMI) monomer and a haloalkane initiator, is presented. Due to the dynamic nature of the r-DA reaction of FMI, the release of maleimide (MI) and the subsequent copolymerization of MI can be regulated by tuning the temperature and stereochemistry during its SCVCP.

中文翻译：

基于 Diels-Alder 化学的“潜在”异构体策略一锅结构控制合成超支化聚合物

提出了一种“单锅”策略，用于基于“潜在”异构体的结构控制合成超支化聚合物，其中包含呋喃保护的马来酰亚胺 (FMI) 单体和卤代烷引发剂。由于 FMI 的r -DA 反应的动态特性，马来酰亚胺 (MI) 的释放和随后的 MI 共聚可以通过调节其 SCVCP 期间的温度和立体化学来调节。

更新日期：2022-08-18

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