沸石咪唑酯骨架 (ZIF) 衍生的纳米材料及其用于高级二次电池和电催化的杂化物,The Chemical Record

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沸石咪唑酯骨架 (ZIF) 衍生的纳米材料及其用于高级二次电池和电催化的杂化物
The Chemical Record ( IF 7.0 ) Pub Date : 2022-08-12 , DOI: 10.1002/tcr.202200105
Xiaotong Li _{1,

2} , Huajian Liang ₂ , Xinlong Liu ₂ , Yufei Zhang ₁ , Zili Liu ₂ , Haosen Fan ₁

Affiliation

咪唑沸石骨架（ZIFs）作为一类典型的金属有机骨架（MOFs），由于其化学结构稳定、合成简便、环境友好等优点，在储能和能源领域引起了广泛关注。在 ZIFs 家族中，锌基咪唑酯骨架（ZIF-8）和钴基咪唑酯骨架（ZIF-67）被认为是有前途的 ZIFs 材料，这归因于其可调的孔隙率、稳定的结构和理想的导电性。迄今为止，各种 ZIF-8 和 ZIF67 衍生材料，包括碳材料、金属氧化物、硫化物、硒化物、碳化物和磷化物，已成功地以 ZIFs 为模板合成，并被评估为用于二次电池和电催化的有前景的电极材料。本综述为理解 ZIFs 衍生物的性能优化和应用前景提供了有效的指导，特别关注结构优化及其在二次电池和电催化中的应用。详细介绍了 ZIF-8、ZIF-67 和 ZIF-8@ZIF-67 衍生纳米材料及其杂化物（包括碳材料、金属氧化物、碳化物、氧化物、硫化物、硒化物、用于高性能二次电池和电催化的磷化物。

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Zeolite Imidazolate Frameworks (ZIFs) Derived Nanomaterials and their Hybrids for Advanced Secondary Batteries and Electrocatalysis

Zeolite imidazolate frameworks (ZIFs), as a typical class of metal-organic frameworks (MOFs), have attracted a great deal of attention in the field of energy storage and conversation due to their chemical structure stability, facile synthesis and environmental friendliness. Among of ZIFs family, the zinc-based imidazolate framework (ZIF-8) and cobalt-based imidazolate framework (ZIF-67) have considered as promising ZIFs materials, which attributed to their tunable porosity, stable structure, and desirable electrical conductivity. To date, various ZIF-8 and ZIF67 derived materials, including carbon materials, metal oxides, sulfides, selenides, carbides and phosphides, have been successfully synthesized using ZIFs as templates and evaluated as promising electrode materials for secondary batteries and electrocatalysis. This review provides an effective guide for the comprehension of the performance optimization and application prospects of ZIFs derivatives, specifically focusing on the optimization of structure and their application in secondary batteries and electrocatalysis. In detail, we present recent advances in the improvement of electrochemical performance of ZIF-8, ZIF-67 and ZIF-8@ZIF-67 derived nanomaterials and their hybrids, including carbon materials, metal oxides, carbides, oxides, sulfides, selenides, and phosphides for high-performance secondary batteries and electrocatalysis.

更新日期：2022-08-12

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