Ligand-to-Metal Charge Transfer (LMCT) Photochemistry at 3d-Metal Complexes: An Emerging Tool for Sustainable Organic Synthesis,ChemCatChem

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Ligand-to-Metal Charge Transfer (LMCT) Photochemistry at 3d-Metal Complexes: An Emerging Tool for Sustainable Organic Synthesis
ChemCatChem ( IF 3.8 ) Pub Date : 2022-08-11 , DOI: 10.1002/cctc.202200916
Fabio Juliá ₁

Affiliation

Photocatalysis: The population of ligand-to-metal charge-transfer (LMCT) excited states upon light irradiation of abundant and inexpensive 3d-metal complexes represents an effective platform to access open-shell intermediates of high synthetic value. This review provides guidelines for the utilization of this inner-sphere reactivity, a comparison of its distinct profile in comparison with photoredox catalysis, and a collection of the most relevant achievements applied to organic synthesis.

中文翻译：

3d-金属配合物的配体到金属电荷转移 (LMCT) 光化学：可持续有机合成的新兴工具

光催化：在光照射丰富且廉价的 3d 金属配合物时，配体-金属电荷转移 (LMCT) 激发态的群体代表了获得高合成价值的开壳中间体的有效平台。这篇综述为利用这种内球反应性提供了指导，将其与光氧化还原催化的独特特征进行了比较，并收集了应用于有机合成的最相关成就。

更新日期：2022-08-11

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