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Synthetic Studies toward the C14–C29 Fragment of Mirabalin
Organic Letters ( IF 4.9 ) Pub Date : 2016-09-07 00:00:00 , DOI: 10.1021/acs.orglett.6b02162 Johan Cornil 1 , Pierre-Georges Echeverria 2 , Sébastien Reymond 1 , Phannarath Phansavath 2 , Virginie Ratovelomanana-Vidal 2 , Amandine Guérinot 1 , Janine Cossy 1
Organic Letters ( IF 4.9 ) Pub Date : 2016-09-07 00:00:00 , DOI: 10.1021/acs.orglett.6b02162 Johan Cornil 1 , Pierre-Georges Echeverria 2 , Sébastien Reymond 1 , Phannarath Phansavath 2 , Virginie Ratovelomanana-Vidal 2 , Amandine Guérinot 1 , Janine Cossy 1
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A convergent synthesis of one isomer of the C14–C29 fragment of mirabalin is disclosed. The key steps include a Marshall allenylation, a Mukaiyama aldol reaction and a Crimmins aldolization, which allow the control of 10 out of 25 stereogenic centers present in the molecule.
中文翻译:
对米拉巴林C14–C29片段的合成研究
公开了米拉巴林C14–C29片段的一个异构体的会聚合成。关键步骤包括马歇尔烯丙基化,Mukaiyama aldol反应和Crimmins aldolization,这可以控制分子中存在的25个立体异构中心中的10个。
更新日期:2016-09-07
中文翻译:
对米拉巴林C14–C29片段的合成研究
公开了米拉巴林C14–C29片段的一个异构体的会聚合成。关键步骤包括马歇尔烯丙基化,Mukaiyama aldol反应和Crimmins aldolization,这可以控制分子中存在的25个立体异构中心中的10个。