Single-Layer 2D Ni−BDC MOF Obtained in Supercritical CO2-Assisted Aqueous Solution,Chemistry - A European Journal

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Single-Layer 2D Ni−BDC MOF Obtained in Supercritical CO2-Assisted Aqueous Solution
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-08-05 , DOI: 10.1002/chem.202201811
Hongwei Chang ₁ , Yannan Zhou ₁ , Xiaoli Zheng ₁ , Wei Liu ₂ , Qun Xu _{1,

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Affiliation

A chip off the old MOF: A CO₂ molecule can exchange with the lattice-coordinated H₂O molecules and side-on coordinate with the metal Ni sites on Ni−BDC surface simultaneously; finally this breaks the interlayer hydrogen bond of bulk Ni−BDC and helps to form 2D MOF.

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