Fe-Catalyzed Amidation of Allylic Alcohols by Borrowing Hydrogen Catalysis,Chemistry - A European Journal

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Fe-Catalyzed Amidation of Allylic Alcohols by Borrowing Hydrogen Catalysis
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-07-28 , DOI: 10.1002/chem.202201829
Xiaoyun Wu ₁ , Wei Ma _{1,

2} , Weijun Tang ₁ , Dong Xue ₁ , Jianliang Xiao ₃ , Chao Wang ₁

Affiliation

The amidation of allylic alcohols with chiral tert-butylsulfinamide catalyzed by an Earth-abundant Fe complex via a borrowing hydrogen pathway has been developed. With water as the only by-product, a range of synthetically useful chiral sulfinamide olefin derivatives were obtained under mild reaction conditions with exclusive linear selectivity and retention of enantioselectivity.

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