Electrocatalytic Hydrogenation of 5-Hydroxymethylfurfural Promoted by a Ru1Cu Single-Atom Alloy Catalyst,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Electrocatalytic Hydrogenation of 5-Hydroxymethylfurfural Promoted by a Ru1Cu Single-Atom Alloy Catalyst
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-07-25 , DOI: 10.1002/anie.202209849
Kaiyue Ji ₁ , Ming Xu ₂ , Si-Min Xu ₂ , Ye Wang ₁ , Ruixiang Ge ₁ , Xiaoyu Hu ₃ , Xiaoming Sun ₂ , Haohong Duan _{1,

4}

Affiliation

Electrocatalytic hydrogenation (ECH) of 5-hydroxymethylfurfural (HMF) to 2,5-dihydroxymethylfuran (DHMF) was achieved over a Ru₁Cu single-atom alloy (SAA) catalyst with isolated Ru atoms on Cu nanowires. Single-atom Ru promotes the dissociation of water to produce H* species that effectively react with HMF to afford DHMF. This work offers a catalyst design model for highly efficient ECH of biomass via single-atom alloying.

中文翻译：

Ru1Cu单原子合金催化剂促进5-羟甲基糠醛电催化加氢

5-羟甲基糠醛 (HMF) 电催化氢化 (ECH) 为 2,5-二羟甲基呋喃 (DHMF) 是在 Ru ₁ Cu 单原子合金 (SAA) 催化剂上实现的，该催化剂在 Cu 纳米线上具有孤立的 Ru 原子。单原子 Ru 促进水的离解产生 H* 物质，该物质可有效地与 HMF 反应以提供 DHMF。这项工作为通过单原子合金化的生物质高效 ECH 提供了催化剂设计模型。

更新日期：2022-07-25

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南