Nanoscale Research Letters ( IF 5.5 ) Pub Date : 2022-07-22 , DOI: 10.1186/s11671-022-03703-6 Yi-Tsung Chang , Lingun Zhang , Mu-Jen Lai , Wei-Chen Chiang , Lung-Chien Chen
This paper elucidates the increased luminescence efficiency of CsPbBr2.1Cl0.9 sky-blue perovskite light-emitting diodes (PeLEDs) achieved through the interface modification of 3,4 ethylenedioxythiophene (PEDOT):polystyrene sulfonic acid (PSS)/quasi-two-dimensional (QTD) perovskite using CsCl and CsBr materials, respectively. QTD films were fabricated using ratios of CsPbBr2.1Cl0.9 doped with phenethylamine hydrobromide (PEABr) at 60%, 80%, and 100%. The solvent dimethyl sulfide (C2H6OS) was employed under the excitation of ambient and 365-nm laser lights. The PeLED structure was composed of Al/LiF/2,2',2"-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi)/CsPbBr2.1Cl0.9:PEABr/interface modification layer/PEDOT:PSS/ITO glass. The optimized results revealed that the luminance, current efficiency, and external quantum efficiency of the QTD CsPbBr2.1Cl0.9:80% PEABr PeLED with the CsCl interface modification additive was 892 cd/m2, 3.87 cd/A, and 5.56%, respectively.
中文翻译:
具有界面改性层的高性能准二维 CsPbBr2.1Cl0.9:PEABr 钙钛矿天蓝色 LED
本文阐述了通过3,4乙烯二氧噻吩(PEDOT):聚苯乙烯磺酸(PSS)/准二维( QTD)分别使用CsCl和CsBr材料的钙钛矿。使用掺杂比例为 60%、80% 和 100% 的氢溴酸苯乙胺 (PEABr) 的 CsPbBr 2.1 Cl 0.9制备 QTD 薄膜。在环境光和365 nm激光的激发下使用溶剂二甲基硫醚(C 2 H 6 OS)。 PeLED结构由Al/LiF/2,2',2"-(1,3,5-苯并三基)-三(1-苯基-1-H-苯并咪唑)(TPBi)/CsPbBr 2.1 Cl 0.9 :PEABr组成/界面改性层/PEDOT:PSS/ITO玻璃 优化结果表明,添加CsCl界面改性添加剂的QTD CsPbBr 2.1 Cl 0.9 :80% PEABr PeLED的亮度、电流效率和外量子效率为892 cd/m。 2 、分别为3.87cd/A和5.56%。