当前位置：
X-MOL 学术
›
Energy Fuels
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Generation and Regeneration of the C(sp3)–F Bond and 1,4-NADH/NADPH via Newly Designed S-gC3N4@Fe2O3/LC Photocatalysts under Solar Light
Energy & Fuels ( IF 5.2 ) Pub Date : 2022-07-19 , DOI: 10.1021/acs.energyfuels.1c03697
Satyam Singh 1 , Rajesh K. Yadav 1 , Tae Wu Kim 2 , Chandani Singh 1 , Pooja Singh 1 , Surabhi Chaubey 1 , Atul. P. Singh 3 , Jin-Ook Baeg 4 , Sarvesh K. Gupta 5 , Dhanesh Tiwary 6
Energy & Fuels ( IF 5.2 ) Pub Date : 2022-07-19 , DOI: 10.1021/acs.energyfuels.1c03697
Satyam Singh 1 , Rajesh K. Yadav 1 , Tae Wu Kim 2 , Chandani Singh 1 , Pooja Singh 1 , Surabhi Chaubey 1 , Atul. P. Singh 3 , Jin-Ook Baeg 4 , Sarvesh K. Gupta 5 , Dhanesh Tiwary 6
Affiliation
|
Due to the pharmaceutical, biological, physical, and chemical properties of fluorinated compounds and 1,4-NADH/NADPH, these species have attracted a lot of attention from researchers across the chemical society. Despite their crucial significance, present methods of regenerating cofactors (1,4-NADH/NADPH) as well as inserting fluorine into organic compounds suffer from ruthless drawbacks. Herein, we designed a highly efficient S-gC3N4@Fe2O3/LC photocatalyst, and its in situ generations were accomplished by calcinations of Fe2O3, melamine (M), thiophenol (T), and lignin carbon (LC). The Fe2O3 part performs similar to an additional light harvester, gifting utmost photo-generated electrons, whereas the carbon part bridges a “thoroughfare” to make easy electron transfer from Fe2O3 to S-gC3N4 (Schemes 1 and 2). Therefore, the newly designed S-gC3N4@Fe2O3/LC photocatalyst is more efficient for the generation and regeneration of the C(sp3)–F bond and 1,4-NADH/NADPH due to its surface active sites and defects.
中文翻译：
太阳光下新设计的 S-gC3N4@Fe2O3/LC 光催化剂产生和再生 C(sp3)-F 键和 1,4-NADH/NADPH
由于含氟化合物和1,4-NADH/NADPH的药学、生物学、物理和化学性质，这些物种引起了化学界研究人员的广泛关注。尽管它们具有至关重要的意义，但目前再生辅因子 (1,4-NADH/NADPH) 以及将氟插入有机化合物中的方法仍存在无情的缺点。在此，我们设计了一种高效的 S-gC 3 N 4 @Fe 2 O 3 /LC 光催化剂，其原位生成是通过 Fe 2 O 3、三聚氰胺 (M)、苯硫酚 (T) 和木质素碳的煅烧完成的。 (LC)。Fe 2 O 3部分的性能类似于额外的光收集器，提供最大的光生电子，而碳部分桥接“通道”，使电子从 Fe 2 O 3轻松转移到 S-gC 3 N 4（方案 1 和 2）。因此，新设计的 S-gC 3 N 4 @Fe 2 O 3 /LC 光催化剂由于其表面活性而更有效地生成和再生 C(sp 3 )-F 键和 1,4-NADH/NADPH网站和缺陷。
更新日期：2022-07-19
中文翻译：
太阳光下新设计的 S-gC3N4@Fe2O3/LC 光催化剂产生和再生 C(sp3)-F 键和 1,4-NADH/NADPH
由于含氟化合物和1,4-NADH/NADPH的药学、生物学、物理和化学性质，这些物种引起了化学界研究人员的广泛关注。尽管它们具有至关重要的意义，但目前再生辅因子 (1,4-NADH/NADPH) 以及将氟插入有机化合物中的方法仍存在无情的缺点。在此，我们设计了一种高效的 S-gC 3 N 4 @Fe 2 O 3 /LC 光催化剂，其原位生成是通过 Fe 2 O 3、三聚氰胺 (M)、苯硫酚 (T) 和木质素碳的煅烧完成的。 (LC)。Fe 2 O 3部分的性能类似于额外的光收集器，提供最大的光生电子，而碳部分桥接“通道”，使电子从 Fe 2 O 3轻松转移到 S-gC 3 N 4（方案 1 和 2）。因此，新设计的 S-gC 3 N 4 @Fe 2 O 3 /LC 光催化剂由于其表面活性而更有效地生成和再生 C(sp 3 )-F 键和 1,4-NADH/NADPH网站和缺陷。
京公网安备 11010802027423号