Radical deuteration,Chemical Society Reviews

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Radical deuteration
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2022-07-19 , DOI: 10.1039/d1cs00907a
Nian Li ₁ , Yantao Li ₁ , Xiaopeng Wu ₁ , Chengjian Zhu _{1,

2} , Jin Xie _{1,

3}

Affiliation

Deuterated chemicals are becoming irreplaceable in pharmaceutical engineering, material science and synthetic chemistry. Many excellent reviews have discussed acid/base-dependent or metal-catalyzed deuteration reactions, but radical deuterations have been discussed less. With the development of radical chemistry, there has been a rapid growth in radical deuterium-labelling technology. Diverse mild, cheap and efficient strategies for deuterium atom installation have been reported, and this review summarizes the recent achievements of radical deuteration classified by the reaction types.

中文翻译：

自由基氘

氘代化学品在制药工程、材料科学和合成化学中正变得不可替代。许多优秀的评论都讨论了酸/碱依赖性或金属催化的氘化反应，但很少讨论自由基氘化反应。随着自由基化学的发展，自由基氘标记技术迅速发展。已经报道了多种温和、廉价和高效的氘原子安装策略，本综述总结了按反应类型分类的自由基氘化的最新成就。

更新日期：2022-07-19

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