The rapid and precise detection of hydrogen peroxide has recently been a hot research in non-enzymatic electrochemical sensors. Herein, peanut shell-like Cu-Mo₂C/Mo₃P/C composite was simply prepared by in-situ simultaneous phosphorization and carbonization of [Cu(P₄Mo₆)]-based metal-organic framework (MOF) under N₂/H₂ atmosphere. Then, the above nanomaterials were deposited on glassy carbon electrode (GCE) surface through facile drop coating method, thus fabricating a highly efficient non-enzymatic H₂O₂ electrochemical sensor. In phosphate buffer solution (PBS, pH = 7.4), the Cu-Mo₂C/Mo₃P/C/GCE exhibits high sensitivity (653.2 μA mM^-1 cm^-2) and low detection limit (37 nM) to H₂O₂. Its amperometric response is 1.94, 3.27 and 4.71 times bigger than that of Mo₂C/Mo₃P/C/GCE, Mo₃P/GCE and Mo₂C/GCE. Such good electrochemical sensing performance is mainly ascribed to the synergism of unique microstructure, platinum-like Mo₂C and Mo₃P co-combination, together with copper and carbon dual-doping. Moreover, it can realize the satisfactory detection of H₂O₂ in human serum, disinfectant and contact lens solution, indicating the potential application in the fields of environmental monitoring and biochemical analysis.

过氧化氢的快速精确检测是近来非酶电化学传感器的研究热点。本文通过[Cu(P ₄ Mo ₆ )]基金属有机骨架(MOF)在N气氛下原位同时磷化和碳化制备花生壳状Cu-Mo ₂ C/Mo ₃ P/C复合材料。₂ /H ₂大气压。然后，通过简易滴涂法将上述纳米材料沉积在玻碳电极（GCE）表面，从而制备出高效的非酶H ₂ O ₂电化学传感器。在磷酸盐缓冲溶液（PBS，pH = 7.4）中，Cu-Mo ₂C/Mo _{3 P/C/GCE对H 2} O ₂表现出高灵敏度（653.2 μA mM ^-1 cm ^-2）和低检测限（37 nM）。_{其电流响应是Mo 2} C/Mo ₃ P/C/GCE、Mo ₃ P/GCE和Mo ₂ C/GCE的1.94、3.27和4.71倍。这种良好的电化学传感性能主要归功于独特的微观结构、类铂 Mo ₂ C 和 Mo ₃ P 的共结合以及铜和碳双掺杂的协同作用。而且，它可以实现对H ₂ O _{2的满意检测。}在人血清、消毒剂和隐形眼镜溶液中，表明在环境监测和生化分析领域的潜在应用。