当前位置: X-MOL 学术Synthesis › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Aryne Annulations for the Synthesis of Carbocycles and Heterocycles: An Updated Review
Synthesis ( IF 2.2 ) Pub Date : 2022-07-12 , DOI: 10.1055/a-1863-8622
Manashi Sarmah 1 , Hemanta Hazarika 1 , Pranjal Gogoi 1
Affiliation  

Carbocycles and heterocycles are highly relevant structural moieties that have found countless applications in interdisciplinary areas. In this regard, the interesting chemistry of arynes has been embraced by researchers for the synthesis of structurally different polycyclic systems, i.e. carbocycles and heterocycles. In this review, we intended to provide a comprehensive overview on the annulative approach considering Kobayashi’s aryne intermediate as the key reactive species with diverse nucleophilic and electrophilic partners. The review highlights the different aryne annulation reactions adopted for the synthesis of carbocycles and heterocycles (covering articles mainly from around 2010), showcasing their viability towards broad range of substrates bearing diverse functionalities.

1 Introduction

2 Synthesis of Carbocycles

3 Synthesis of Heterocycles

4 Conclusions



中文翻译:

用于合成碳环和杂环的 Aryne 环化:最新评论

碳环和杂环是高度相关的结构部分,已在跨学科领域发现无数应用。在这方面,芳烃的有趣化学已被研究人员用于合成结构不同的多环系统,碳环和杂环。在这篇综述中,我们打算全面概述考虑小林的芳烃中间体作为具有多种亲核和亲电伙伴的关键活性物质的环化方法。该综述重点介绍了用于合成碳环和杂环的不同芳烃环化反应(主要涵盖 2010 年左右的文章),展示了它们对具有多种功能的广泛底物的可行性。

1 简介

2 碳环的合成

3 杂环的合成

4。结论

更新日期:2022-07-13
down
wechat
bug