Hexagonal Planar [B6H6] within a [B6H12] Borate Complex: Structure and Bonding of [(Cp*Ti)2(μ-ɳ6 : ɳ6-B6H6)(μ-H)6],Angewandte Chemie International Edition

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Hexagonal Planar [B6H6] within a [B6H12] Borate Complex: Structure and Bonding of [(Cp*Ti)2(μ-ɳ6 : ɳ6-B6H6)(μ-H)6]
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-30 , DOI: 10.1002/anie.202208293
Sourav Kar ₁ , Subhash Bairagi ₁ , Anagha Haridas ₁ , Gaurav Joshi ₂ , Eluvathingal D Jemmis ₂ , Sundargopal Ghosh ₁

Affiliation

A hexagonal borane [B₆H₆] ring supported by six B−H−Ti bonds in the coordination sphere of {Cp*Ti} fragments is formed from the reaction of [Cp*TiCl₃] with [LiBH₄ ⋅ THF] followed by thermolysis in presence of an excess of [BH₃ ⋅ THF].

中文翻译：

[B6H12] 硼酸盐配合物中的六角平面 [B6H6]：[(Cp*Ti)2(μ-ɳ6 : ɳ6-B6H6)(μ-H)6] 的结构和键合

_{由[Cp*TiCl 3} ] 与[LiBH ₄ ⋅ THF]反应形成的六角硼烷[B ₆ H ₆ ] 环由{Cp*Ti} 片段的配位域中的六个B-H-Ti 键支撑通过在过量 [BH ₃ ⋅ THF] 的存在下进行热解。

更新日期：2022-06-30

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