Superhydrophobic coatings were successfully fabricated on steel substrates using potentiostatic electrodeposition of Ni and Ni-graphene, Ni-G, coatings followed by immersion in an ethanolic solution of stearic acid, SA. Rice straw, an environmentally friendly biomass resource, was used to synthesize high-quality graphene. The Raman spectra proved the high quality of the produced graphene. The Fourier transform infrared spectroscopy, FTIR, results showed that the Ni coating grafted with stearic acid, Ni-SA, and the Ni-G composite grafted with stearic acid, Ni-G-SA, were successfully deposited on the steel substrate. The scanning electron microscope, SEM, results showed that the prepared superhydrophobic coatings exhibit micro-nano structures. The wettability results revealed that the values of contact angles, CAs, for Ni-SA and Ni-G-SA coatings are 155.7° and 161.4°, while the values of sliding angles, SAs, for both coatings are 4.0° and 1.0°, respectively. The corrosion resistance, chemical stability, and mechanical abrasion resistance of the Ni-G-SA coating were found to be greater than those of the Ni-SA coating.