NHC–alcohol adduct-mediated photocatalytic deoxygenation for the synthesis of 6-phenanthridine derivatives,Organic & Biomolecular Chemistry

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NHC–alcohol adduct-mediated photocatalytic deoxygenation for the synthesis of 6-phenanthridine derivatives
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2022-06-21 , DOI: 10.1039/d2ob00814a
Xueji Ma ₁ , Qingyun Wang ₁ , Jinge Wu ₁ , Liyuan Zhang ₁ , Aili Sun ₁ , Zhanyong Wang ₁

Affiliation

NHC–alcohol adduct-mediated deoxygenation of alcohols under photocatalytic conditions is described. This process provides various alkyl radicals, which can react with 2-isocyanobiaryls to afford 6-substituted phenanthridine derivatives in moderate to good yields. This method offered the first example of directly using alcohols as radical sources for 6-phenanthridine synthesis.

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