Abstract

A catalyst- and additive-free hydrolysis of alkenyl fluorosulfonamides is achieved, providing an efficient approach for the synthesis of various aryl ketones in moderate to excellent yields. This reaction exhibits broad functional group compatibility without the formation of undesired desulfonation compounds. Moreover, the procedure operates under the mild conditions avoiding the use of additional metal catalysts or potential security risk substrate (vinyl azide), and the reaction finishes in short reaction time (30 min) at room temperate.

中文翻译：

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乙烯基氟磺酰胺：一种实用的乙烯基亲电子试剂，用于在无催化剂和无添加剂条件下温和高效地合成酮

摘要

实现了烯基氟磺酰胺的无催化剂和无添加剂水解，为以中等至优异的收率合成各种芳基酮提供了一种有效的方法。该反应表现出广泛的官能团相容性，而不会形成不希望的脱磺化化合物。此外，该过程在温和的条件下进行，避免使用额外的金属催化剂或潜在的安全风险底物（叠氮化乙烯），并且反应在室温下的反应时间很短（30分钟）内完成。