Controlling the Flexibility of MIL-88A(Sc) Through Synthetic Optimisation and Postsynthetic Halogenation,Chemistry - A European Journal

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Controlling the Flexibility of MIL-88A(Sc) Through Synthetic Optimisation and Postsynthetic Halogenation
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-06-01 , DOI: 10.1002/chem.202201364
Catherine A Walshe ₁ , Alexander J R Thom ₁ , Claire Wilson ₁ , Sanliang Ling ₂ , Ross S Forgan ₁

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The flexibility of the MOF MIL-88A(Sc) is described and compared to its well-established Fe analogue. Its breathing behaviour can be controlled through installation of formate bridges during synthesis that ensure rigidity by structural buttressing, or by postsynthetic bromination of the fumarate linker to induce rigidity by the steric influence of the bulky linker substituents.

中文翻译：

通过合成优化和合成后卤化控制 MIL-88A(Sc) 的灵活性

描述了MOF MIL-88A(Sc) 的灵活性，并与其成熟的 Fe 类似物进行了比较。其呼吸行为可以通过在合成过程中安装甲酸盐桥来控制，通过结构支撑来确保刚性，或者通过富马酸酯连接基的合成后溴化来通过大连接基取代基的空间影响来诱导刚性。

更新日期：2022-06-01

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