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Guanine Analogue-Based Assemblies: Construction and Luminescence Functions
Langmuir ( IF 3.7 ) Pub Date : 2022-06-01 , DOI: 10.1021/acs.langmuir.2c00705 Ping Qi 1 , Mengjiao Yi 1 , Aixin Song 1 , Jingcheng Hao 1
Langmuir ( IF 3.7 ) Pub Date : 2022-06-01 , DOI: 10.1021/acs.langmuir.2c00705 Ping Qi 1 , Mengjiao Yi 1 , Aixin Song 1 , Jingcheng Hao 1
Affiliation
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As one of the natural nucleobases, guanine has attracted increasing interest in molecular self-assembly science because of its abundant interaction sites and high electron cloud density. Guanines, guanine derivatives, and guanine-rich DNA sequence are able to self-assemble into versatile aggregate structures by the means of hydrogen bonds and π–π, ion–dipole, solvophobic, and electrostatic interactions. Recent advances have shown that many guanine analogue-based (G-based) luminescent aggregates exhibit promising applications for fluorescent and chemiluminescent sensing and circularly polarized luminescence (CPL). This perspective summarizes the state-of-art strategies for constructing G-based assemblies and presents representative examples for luminescence functions. Finally, the inspirations are provided for exploiting unique G-based systems and luminescent G-based assemblies.
中文翻译：
基于鸟嘌呤类似物的组件：构造和发光功能
作为天然核碱基之一，鸟嘌呤因其丰富的相互作用位点和高电子云密度而越来越引起人们对分子自组装科学的兴趣。鸟嘌呤、鸟嘌呤衍生物和富含鸟嘌呤的 DNA 序列能够通过氢键和 π-π、离子-偶极子、疏溶剂和静电相互作用自组装成多种聚集结构。最近的进展表明，许多基于鸟嘌呤类似物 (G-based) 的发光聚集体在荧光和化学发光传感以及圆偏振发光 (CPL) 方面具有广阔的应用前景。该观点总结了构建基于 G 的组件的最新策略，并提供了发光功能的代表性示例。最后，
更新日期：2022-06-01
中文翻译：
基于鸟嘌呤类似物的组件：构造和发光功能
作为天然核碱基之一，鸟嘌呤因其丰富的相互作用位点和高电子云密度而越来越引起人们对分子自组装科学的兴趣。鸟嘌呤、鸟嘌呤衍生物和富含鸟嘌呤的 DNA 序列能够通过氢键和 π-π、离子-偶极子、疏溶剂和静电相互作用自组装成多种聚集结构。最近的进展表明，许多基于鸟嘌呤类似物 (G-based) 的发光聚集体在荧光和化学发光传感以及圆偏振发光 (CPL) 方面具有广阔的应用前景。该观点总结了构建基于 G 的组件的最新策略，并提供了发光功能的代表性示例。最后，
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