Combinatorial Self-Assembly of Coordination Cages with Systematically Fine-Tuned Cavities for Efficient Co-Encapsulation and Catalysis,Angewandte Chemie International Edition

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Combinatorial Self-Assembly of Coordination Cages with Systematically Fine-Tuned Cavities for Efficient Co-Encapsulation and Catalysis
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-05-21 , DOI: 10.1002/anie.202204732
Shao-Chuan Li _{1,

2} , Li-Xuan Cai _{1,

2} , Maochun Hong _{1,

2} , Qihui Chen _{1,

2} , Qing-Fu Sun _{1,

2}

Affiliation

A combinatorial self-assembly approach gives rise to a family of palladium-organic cages featuring systematically fine-tuned shapes and cavities. Emergent guest-binding and catalytic functions were observed that are due to the fusion of two half cavities on the heteroleptic cages from their parent homoleptic cages.

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