Direct aziridination of a nitrostyrene is achieved upon treatment with an alkylamine and N-chlorosuccinimide. The reaction is initiated by the Michael addition of amine to nitroalkene. Subsequent N-chlorination and nucleophilic substitution at the nitrogen atom afford 1-alkyl-2-nitroaziridine diastereoselectively. This reaction mechanism was clarified by NMR studies.

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中文翻译：

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N-氯代琥珀酰亚胺介导的硝基烯烃氮丙啶化机理研究

在用烷基胺和N-氯代琥珀酰亚胺处理后实现硝基苯乙烯的直接氮丙啶化。该反应由胺与硝基烯烃的迈克尔加成引发。随后在氮原子上进行N-氯化和亲核取代，非对映选择性地得到 1-烷基-2-硝基氮丙啶。核磁共振研究阐明了这种反应机理。

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