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Microwave-assisted synthesis to prepare metal-organic framework for luminescence thermometry
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2022-05-16 , DOI: 10.1016/j.jssc.2022.123183
Alia Mansar , Hélène Serier-Brault

The lanthanide metal-organic framework, La1.23Na0.30(1,3-BDC)2(H2O)·4H2O (1,3-BDC: 1,3-benzenedicarboxylate), has been for the first time synthesized under microwave-assisted hydrothermal conditions with a synthesis duration of 5 min. The substitution of La3+ by Eu3+ and Tb3+ was possible until a maximal content of 10%.mol and the investigation of luminescence properties reveals that emitting cations can be located in the chains formed by the LnO10 polyhedra but also into the polar channels proposed by the structure, where some La3+ crystallographic sites are also available. Finally, when codoped by Eu3+ and Tb3+, the materials exhibit thermometric properties in the cryogenic range with a maximal relative thermal sensitivity around 1% K−1 at 80 K.



中文翻译:

微波辅助合成制备用于发光测温的金属有机骨架

镧系金属有机骨架 La 1.23 Na 0.30 (1,3-BDC) 2 (H 2 O)·4H 2 O (1,3-BDC: 1,3-benzodicarboxylate) 首次合成微波辅助水热条件,合成持续时间为 5 分钟。用 Eu 3+和 Tb 3+取代 La 3+是可能的,直到最大含量为 10%.mol,发光特性的研究表明,发光的阳离子可以位于由 LnO 10多面体形成的链中,也可以位于该结构提出的极性通道,其中一些 La 3+晶体学站点也可用。最后,当Eu 3+和Tb 3+共掺杂时,材料在低温范围内表现出测温特性,在80 K时最大相对热灵敏度约为1% K -1 。

更新日期:2022-05-16
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