The path-selectivity and stereoselectivity of gridization pathways into fluorene-based drawing hand grids (DHGs-F) are precisely modulated through tuning acid conditions and side-chain effects. BF₃·OEt₂ supports the realization of the gridization path (rac-DHG1-F, yield: 82%, meso-DHG1-F, yield: 11%). On the contrary, CF₃SO₃H will lead to the enhancements in polymerization pathways (about 85% yield). When the side chain is a methoxyl group, rac-DHG1-F and meso-DHG1-F will be obtained. However, when the side chain is a group without an oxygen atom, only rac-DHGs-F can be obtained (de = 100%). Moreover, through excitonic physical properties, rac-DHGs-F exhibits a more π-electronic delocalization, potentially serving as the intriguing tactic strategy to modulate the optoelectronic properties.

通过调整酸性条件和侧链效应，可以精确调节基于芴的绘图手网格 (DHGs-F) 的网格化路径的路径选择性和立体选择性。BF ₃ ·OEt ₂支持网格化路径的实现（rac -DHG1-F, yield: 82%, meso -DHG1-F, yield: 11%）。相反，CF ₃ SO ₃ H 将导致聚合途径的增强（产率约为85%）。当侧链为甲氧基时，会得到外消旋-DHG1-F和内消旋-DHG1-F。但是，当侧链是没有氧原子的基团时，只能得到rac -DHGs-F ( de= 100%）。此外，通过激子物理特性，rac -DHGs-F 表现出更多的 π 电子离域，可能作为一种有趣的策略策略来调节光电特性。