Metal organic frameworks (MOFs) are currently gaining considerable attention as heterogeneous catalysts. Since the functionality of the framework and the pore size of the MOFs can be adjusted over a wide range for various catalytic reactions, the usage of these materials as solid catalysts is attractive. One of the preferred catalytic mesoMOFs is MIL-101 (MIL: Material of Institute Lavoisier) family which has been mainly investigated. The large surface area, high pore volumes, and acceptable solvent/thermal stability (MIL-101(Cr) up to 300 °C) have led the MIL-101 family to be considered an ideal and widespread MOF for use as a great heterogeneous catalyst or solid support for a variety of reactions. The objective of this review is to present recent research on the use of the MIL-101 family for heterogeneous catalysis in gas and liquid phase reactions.

中文翻译：

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用于多相催化的 MIL-101 金属有机框架的最新进展

金属有机框架（MOFs）目前作为非均相催化剂获得了相当多的关注。由于骨架的功能和 MOF 的孔径可以在很宽的范围内调节以适应各种催化反应，因此将这些材料用作固体催化剂是很有吸引力的。优选的催化介观 MOF 之一是 MIL-101（MIL：拉瓦锡研究所材料）系列，主要研究该系列。大表面积、高孔体积和可接受的溶剂/热稳定性（MIL-101(Cr) 高达 300 °C）使 MIL-101 系列被认为是理想且广泛使用的 MOF，可用作出色的多相催化剂或各种反应的固体支持物。