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[1,2,4]Triazolo[1,5-d][1,2,4]oxadiazole ring system - a novel building block for creating energetic compounds
Chemical Engineering Journal ( IF 13.3 ) Pub Date : 2022-04-30 , DOI: 10.1016/j.cej.2022.136708
Hui Dou 1 , Peng Chen 1 , Lu Hu 1 , Chunlin He 1, 2, 3 , Siping Pang 1
Affiliation  

Three neutral energetic compounds with a novel oxygen-containing fused ring were synthesized by starting from 4-amino-1,2,5-oxadiazole carbohydroximoyl chloride and 5-bromo-3-nitro-1-H-1,2,4-triazole, their structures fully characterized using multinuclear nuclear magnetic resonance (NMR) spectroscopy, infrared (IR), elemental analysis, and single crystal X-ray structuring. Their decomposition temperature, density and impact sensitivity were measured, their detonation performances were calculated by EXPLO5 v6.05.



中文翻译:

[1,2,4]三唑并[1,5-d][1,2,4]恶二唑环系统 - 一种用于创建高能化合物的新型构件

以 4-氨基-1,2,5-恶二唑羟基肟酰氯和 5-溴-3-硝基-1- H -1,2,4-三唑为原料合成了三种具有新型含氧稠环的中性高能化合物,它们的结构使用多核核磁共振 (NMR) 光谱、红外 (IR)、元素分析和单晶 X 射线结构化进行了充分表征。测量了它们的分解温度、密度和冲击敏感性,用EXPLO5 v6.05计算了它们的爆轰性能。

更新日期:2022-04-30
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