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Total Synthesis of (+)-Cacospongionolide B
Heterocycles ( IF 0.8 ) Pub Date : 2010-01-01 , DOI: 10.3987/com-09-s(s)17 Susumu Kobayashi , Motoko Oshida , Misaki Ono , Atsuo Nakazaki
Heterocycles ( IF 0.8 ) Pub Date : 2010-01-01 , DOI: 10.3987/com-09-s(s)17 Susumu Kobayashi , Motoko Oshida , Misaki Ono , Atsuo Nakazaki
Total synthesis of (+)-cacospongionolide B was achieved. The synthesis involved highly stereoselective C-glycosidation of a glycal derived from D-arabinose with 3-furyl boronic acid in the presence of a palladium catalyst and B-alkyl Suzuki-Miyaura coupling of in situ generated alkylborane prepared by the reaction of vinyl trans-decalin with alkenyl triflate.
中文翻译:
(+)-Cacospongionolide B的全合成
实现了(+)-cacospongionolide B的全合成。该合成涉及在钯催化剂和 B-烷基 Suzuki-Miyaura 偶联的情况下,由 D-阿拉伯糖衍生的糖苷与 3-呋喃基硼酸的高度立体选择性 C-糖苷化反应,通过乙烯基反式反应制备的烷基硼烷萘烷与三氟甲磺酸烯基酯。
更新日期:2010-01-01
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
(+)-Cacospongionolide B的全合成
实现了(+)-cacospongionolide B的全合成。该合成涉及在钯催化剂和 B-烷基 Suzuki-Miyaura 偶联的情况下,由 D-阿拉伯糖衍生的糖苷与 3-呋喃基硼酸的高度立体选择性 C-糖苷化反应,通过乙烯基反式反应制备的烷基硼烷萘烷与三氟甲磺酸烯基酯。