Theory of Exciton Dynamics in Thermally Activated Delayed Fluorescence,ChemPhotoChem

当前位置： X-MOL 学术 › ChemPhotoChem › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Theory of Exciton Dynamics in Thermally Activated Delayed Fluorescence
ChemPhotoChem ( IF 3.0 ) Pub Date : 2022-04-23 , DOI: 10.1002/cptc.202200066
Abel Carreras ₁ , David Casanova _{1,

2}

Affiliation

TADF dynamics: In this work, we model and rationalize the different mechanisms determining reverse intersystem crossing (rISC) rates involved in thermally activated delayed fluorescence. The capacity to populate the singlet manifold from the triplet state depends on interstate energies and interactions. The nature of these couplings [spin-orbit (SOC), hyperfine and spin-vibronic] are dictated by the character of states [local excitations (LE) or charge transfer (CT)], and determine the rISC mechanism.

中文翻译：

热激活延迟荧光中的激子动力学理论

TADF 动力学：在这项工作中，我们对确定热激活延迟荧光所涉及的反向系统间交叉 (rISC) 速率的不同机制进行建模和合理化。从三重态填充单重态流形的能力取决于州际能量和相互作用。这些耦合 [自旋轨道 (SOC)、超精细和自旋振动] 的性质由状态 [局部激发 (LE) 或电荷转移 (CT)] 的特性决定，并决定了 rISC 机制。

更新日期：2022-04-23

点击分享查看原文

点击收藏

阅读更多本刊新发论文