Saving the Energy Loss in Lithium-Mediated Nitrogen Fixation by Using a Highly Reactive Li3N Intermediate for C−N Coupling Reactions,Angewandte Chemie International Edition

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Saving the Energy Loss in Lithium-Mediated Nitrogen Fixation by Using a Highly Reactive Li3N Intermediate for C−N Coupling Reactions
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-04-27 , DOI: 10.1002/anie.202203170
Gao-Feng Chen ₁ , Aleksandr Savateev ₁ , Zihan Song ₁ , Haoyu Wu ₂ , Yevheniia Markushyna ₁ , Lili Zhang ₃ , Haihui Wang ₂ , Markus Antonietti ₁

Affiliation

A successive reaction that yields aryl imides through combining lithium-mediated N₂ fixation and C−N coupling is reported. Instead of simply being hydrolyzed to NH₃ with energy wasted, this work first focuses on electro-synthetic Li₃N from N₂-fixation for the direct synthesis of nitrogen-containing chemicals, which will compensate for the energy consumption of Li plating and make the electrochemical N₂ fixation more economical.

中文翻译：

通过使用高反应活性的 Li3N 中间体进行 C−N 偶联反应，节省锂介导的固氮过程中的能量损失

据报道，通过结合锂介导的 N ₂固定和 CN 偶联，产生芳基酰亚胺的连续反应。这项工作不是简单地水解成NH ₃浪费能量，而是首先关注从N ₂固定电合成Li ₃ N，用于直接合成含氮化学品，这将补偿镀锂的能耗，使电化学N ₂固定更经济。

更新日期：2022-04-27

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