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In Situ Organized Pd and Au Nanoparticles in a Naphthalene-Based Imine-Linked Covalent Triazine Framework for Catalytic Suzuki Reactions and H2 Generation from Formic Acid
ACS Applied Nano Materials ( IF 5.3 ) Pub Date : 2022-04-26 , DOI: 10.1021/acsanm.2c00285 Nasrin Nouruzi 1 , Mohammad Dinari 1 , Behnam Gholipour 2 , Mohaddeseh Afshari 1 , Sadegh Rostamnia 2
ACS Applied Nano Materials ( IF 5.3 ) Pub Date : 2022-04-26 , DOI: 10.1021/acsanm.2c00285 Nasrin Nouruzi 1 , Mohammad Dinari 1 , Behnam Gholipour 2 , Mohaddeseh Afshari 1 , Sadegh Rostamnia 2
Affiliation
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Herein, a naphthalene-based imine-linked covalent triazine framework (NICTF) as a triazine-based covalent organic framework (COF) was obtained. The mesochannels of NICTF COF with a Schiff base condensed bridge are robust multipurpose support. Then, a Pd and Au nanoparticle-decorated NICTF with no aggregation was in situ obtained. The Pd nanoparticle (NP) catalyst exhibited outstanding stability and excellent activity in the Suzuki coupling reactions and H2 generation from formic acid. The Au-based nanocatalyst was applied for an A3-coupling three-component reaction.
中文翻译：
萘基亚胺连接共价三嗪骨架中的原位组织 Pd 和 Au 纳米颗粒用于催化 Suzuki 反应和甲酸制氢
在此，获得了萘基亚胺连接的共价三嗪骨架（NICTF）作为三嗪基共价有机骨架（COF）。具有席夫碱凝聚桥的 NICTF COF 中通道是强大的多用途支持。然后，原位获得了没有聚集的Pd和Au纳米颗粒装饰的NICTF。Pd纳米颗粒（NP）催化剂在Suzuki偶联反应和甲酸生成H 2中表现出优异的稳定性和优异的活性。Au基纳米催化剂用于A 3偶联三组分反应。
更新日期：2022-04-26
中文翻译：
萘基亚胺连接共价三嗪骨架中的原位组织 Pd 和 Au 纳米颗粒用于催化 Suzuki 反应和甲酸制氢
在此，获得了萘基亚胺连接的共价三嗪骨架（NICTF）作为三嗪基共价有机骨架（COF）。具有席夫碱凝聚桥的 NICTF COF 中通道是强大的多用途支持。然后，原位获得了没有聚集的Pd和Au纳米颗粒装饰的NICTF。Pd纳米颗粒（NP）催化剂在Suzuki偶联反应和甲酸生成H 2中表现出优异的稳定性和优异的活性。Au基纳米催化剂用于A 3偶联三组分反应。
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