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Application of 1-(3-Bromo-3,3-difluoroprop-1-ynyl)benzenes in Diels-Alder Reactions: Synthesis ofortho-CF2Br-Substituted Biaryls
Synthesis ( IF 2.2 ) Pub Date : 2008-08-06 , DOI: 10.1055/s-2008-1067221 Valentine Nenajdenko , Günter Haufe , Vasiliy Muzalevskiy , Aleksey Shastin , Elizabeth Balenkova
Synthesis ( IF 2.2 ) Pub Date : 2008-08-06 , DOI: 10.1055/s-2008-1067221 Valentine Nenajdenko , Günter Haufe , Vasiliy Muzalevskiy , Aleksey Shastin , Elizabeth Balenkova
1-(3-Bromo-3,3-difluoroprop-1 1-ynyl)benzenes were found to be good dienophiles in Diels-Alder reactions. Based on this key reaction a new pathway towards biaryls with an ortho-CF 2 Br group was elaborated.
中文翻译：
1-(3-Bromo-3,3-difluoroprop-1-ynyl)苯在狄尔斯-阿尔德反应中的应用：邻-CF2Br-取代的联芳基的合成
1-(3-Bromo-3,3-difluoroprop-1 1-ynyl)苯被发现是Diels-Alder反应中良好的亲双烯体。基于这一关键反应，我们详细阐述了获得具有邻位-CF 2 Br 基团的联芳基化合物的新途径。
更新日期：2008-08-06
中文翻译：
1-(3-Bromo-3,3-difluoroprop-1-ynyl)苯在狄尔斯-阿尔德反应中的应用：邻-CF2Br-取代的联芳基的合成
1-(3-Bromo-3,3-difluoroprop-1 1-ynyl)苯被发现是Diels-Alder反应中良好的亲双烯体。基于这一关键反应，我们详细阐述了获得具有邻位-CF 2 Br 基团的联芳基化合物的新途径。
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