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4,4′-Bis(dichloroiodo)biphenyl and 3-(Dichloroiodo)benzoic Acid: New Recyclable Hypervalent Iodine Reagents for Vicinal Halomethoxylation of Unsaturated Compounds
Synthesis ( IF 2.2 ) Pub Date : 2004-01-01 , DOI: 10.1055/s-2004-831175 Mehman S. Yusubov , Larisa A. Drygunova , Viktor V. Zhdankin
Synthesis ( IF 2.2 ) Pub Date : 2004-01-01 , DOI: 10.1055/s-2004-831175 Mehman S. Yusubov , Larisa A. Drygunova , Viktor V. Zhdankin
4,4'-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid are convenient recyclable hypervalent iodine reagents for vicinal chloromethoxylation or iodomethoxylation of unsaturated compounds. The reactivity of these reagents in the reaction of vicinal halomethoxylation is generally similar to dichloroiodobenzene and the advantage of their use is that the reduced forms of these reagents can be easily separated from the reaction mixture and reused for the regeneration of the reagents.
中文翻译:
4,4'-双(二氯碘)联苯和 3-(二氯碘)苯甲酸:用于不饱和化合物邻位卤甲氧基化的新型可回收高价碘试剂
4,4'-双(二氯碘)联苯和 3-(二氯碘)苯甲酸是方便的可回收高价碘试剂,用于不饱和化合物的邻氯甲氧基化或碘甲氧基化。这些试剂在连位卤代甲氧基化反应中的反应性一般与二氯碘苯相似,使用它们的优点是这些试剂的还原形式可以很容易地从反应混合物中分离出来,重新用于试剂的再生。
更新日期:2004-01-01
中文翻译:
4,4'-双(二氯碘)联苯和 3-(二氯碘)苯甲酸:用于不饱和化合物邻位卤甲氧基化的新型可回收高价碘试剂
4,4'-双(二氯碘)联苯和 3-(二氯碘)苯甲酸是方便的可回收高价碘试剂,用于不饱和化合物的邻氯甲氧基化或碘甲氧基化。这些试剂在连位卤代甲氧基化反应中的反应性一般与二氯碘苯相似,使用它们的优点是这些试剂的还原形式可以很容易地从反应混合物中分离出来,重新用于试剂的再生。