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Plasticity and Ferroelasticity Transitions of Molecular Complex [(C4H9N2)2][Fe3O(O2CH)9] on Heating and Cooling near Room Temperature
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2022-04-12 , DOI: 10.1021/acs.cgd.2c00219
Guo-Hao Ni 1 , Ying-Xi Sun 1 , Cui-Xian Ji 1 , Ya-Wei Jin 2 , Meng-Yuan Liu 1 , Jiong-Peng Zhao 1 , Fu-Chen Liu 1
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2022-04-12 , DOI: 10.1021/acs.cgd.2c00219
Guo-Hao Ni 1 , Ying-Xi Sun 1 , Cui-Xian Ji 1 , Ya-Wei Jin 2 , Meng-Yuan Liu 1 , Jiong-Peng Zhao 1 , Fu-Chen Liu 1
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A new molecular ionic complex, [(C4H9N2)2][Fe3O(O2CH)9] (1), is constructed by an oxo-centered trinuclear iron anion and a semi-rigid ring-like cation 1,4,5,6-tetrahydropyrimidin-ium, which is generated in situ by reacting formic acid and 1,3-propylenediamine. The molecular motion change of anions and cations produces continuously reversible plasticity and ferroelasticity transition on heating and cooling near room temperature.
中文翻译：
分子配合物[(C4H9N2)2][Fe3O(O2CH)9]在室温附近加热和冷却时的塑性和铁弹性转变
一种新的分子离子配合物，[(C 4 H 9 N 2 ) 2 ][Fe 3 O(O 2 CH) 9 ] ( 1 )，由一个氧中心三核铁阴离子和一个半刚性环状阳离子 1,4,5,6-四氢嘧啶鎓，由甲酸和 1,3-丙二胺反应原位生成。阴离子和阳离子的分子运动变化在接近室温的加热和冷却过程中产生连续可逆的塑性和铁弹性转变。
更新日期：2022-04-12
中文翻译：
分子配合物[(C4H9N2)2][Fe3O(O2CH)9]在室温附近加热和冷却时的塑性和铁弹性转变
一种新的分子离子配合物，[(C 4 H 9 N 2 ) 2 ][Fe 3 O(O 2 CH) 9 ] ( 1 )，由一个氧中心三核铁阴离子和一个半刚性环状阳离子 1,4,5,6-四氢嘧啶鎓，由甲酸和 1,3-丙二胺反应原位生成。阴离子和阳离子的分子运动变化在接近室温的加热和冷却过程中产生连续可逆的塑性和铁弹性转变。
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