A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion,Chemistry - A European Journal

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A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-04-07 , DOI: 10.1002/chem.202200893
Zhaowen Dong ₁ , Andrzej Sienkiewicz ₂ , Abdusalom A. Suleymanov ₁ , Cesare Berton ₁ , Farzaneh Fadaei-Tirani ₁ , Rosario Scopelliti ₁ , Kay Severin ₃

Affiliation

Being mesoionic makes the difference: A diselenolene ligand with fundamentally different electronic properties compared to a normal diselenolene is reported. Two stable redox states are accessible: a paramagnetic radical dianion and a diamagnetic monoanion. The ligand was used for the preparation of novel aluminum bis- and tris(diselenolene) complexes.

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