Polyoxometalate-Surfactant Assemblies: Responsiveness to Orthogonal Stimuli,Angewandte Chemie International Edition

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Polyoxometalate-Surfactant Assemblies: Responsiveness to Orthogonal Stimuli
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-04-05 , DOI: 10.1002/anie.202203741
Zhiqin Xia ₁ , Chang-Gen Lin _{1,

2} , Yang Yang ₁ , Yongkang Wang ₁ , Zhanpeng Wu ₃ , Yu-Fei Song _{1,

2} , Thomas P Russell _{4,

5} , Shaowei Shi ₁

Affiliation

Covalently modifying a polyoxometalate with β-cyclodextrin has led to the formation of a polyoxometalate/β-cyclodextrin hybrid. The hybrid, when dissolved in water, can assemble at liquid–liquid interfaces with ligands dissolved in toluene, thereby generating polyoxometalate surfactants (POMSs) with pH, redox or guest–competitive responsiveness.

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