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Conductive Metal–Organic Frameworks for Supercapacitors
Advanced Materials ( IF 27.4 ) Pub Date : 2022-03-31 , DOI: 10.1002/adma.202200999
Liang Niu 1 , Taizheng Wu 2 , Ming Chen 2 , Long Yang 1 , Jingjing Yang 1 , Zhenxiang Wang 1 , Alexei A Kornyshev 3 , Huili Jiang 1 , Sheng Bi 4 , Guang Feng 1
Affiliation  

As a class of porous materials with crystal lattices, metal–organic frameworks (MOFs), featuring outstanding specific surface area, tunable functionality, and versatile structures, have attracted huge attention in the past two decades. Since the first conductive MOF is successfully synthesized in 2009, considerable progress has been achieved for the development of conductive MOFs, allowing their use in diverse applications for electrochemical energy storage. Among those applications, supercapacitors have received great interest because of their high power density, fast charging ability, and excellent cycling stability. Here, the efforts hitherto devoted to the synthesis and design of conductive MOFs and their auspicious capacitive performance are summarized. Using conductive MOFs as a unique platform medium, the electronic and molecular aspects of the energy storage mechanism in supercapacitors with MOF electrodes are discussed, highlighting the advantages and limitations to inspire new ideas for the development of conductive MOFs for supercapacitors.

中文翻译:

用于超级电容器的导电金属有机框架

作为一类具有晶格的多孔材料,金属有机框架(MOFs)具有突出的比表面积、可调的功能和多功能的结构,在过去二十年中引起了广泛的关注。自 2009 年成功合成第一个导电 MOF 以来,导电 MOF 的开发取得了长足的进步,使其可用于电化学储能的各种应用。在这些应用中,超级电容器因其高功率密度、快速充电能力和出色的循环稳定性而受到极大关注。在这里,总结了迄今为止致力于导电 MOF 的合成和设计及其良好的电容性能的努力。使用导电 MOF 作为独特的平台介质,
更新日期:2022-03-31
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