Oxidation of Cyclopentene with Manganese Oxides Octahedral Molecular Sieves with Layer and Tunnel Structures,ChemistrySelect

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Oxidation of Cyclopentene with Manganese Oxides Octahedral Molecular Sieves with Layer and Tunnel Structures
ChemistrySelect ( IF 1.9 ) Pub Date : 2022-03-18 , DOI: 10.1002/slct.202104110
Luis J. Garces ₁ , John Alexander Galeano ₁ , Hector F. Garces ₂ , Steven L. Suib ₃ , Beatriz Hincapie ₁

Affiliation

Manganese oxides type OL-1, OMS-1 and OMS-2 were used for the first time as catalysts in the epoxidation of cyclopentene using the bicarbonate-peroxide system. Layered manganese oxide, OL-1 was the most selective. Impregnation with sodium tungstate reduces selectivity to cyclopentene oxide by blocking the Mn²⁺ active sites.

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