Near-IR Intramolecular Charge Transfer in Strongly Interacting Diphenothiazene-TCBD and Diphenothiazene-DCNQ Push-Pull Triads,Chemistry - A European Journal

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Near-IR Intramolecular Charge Transfer in Strongly Interacting Diphenothiazene-TCBD and Diphenothiazene-DCNQ Push-Pull Triads
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-03-11 , DOI: 10.1002/chem.202200348
Indresh S. Yadav ₁ , Youngwoo Jang ₂ , Yogajivan Rout ₁ , Michael B. Thomas ₂ , Rajneesh Misra ₁ , Francis D'Souza ₃

Affiliation

Charge Transfer. A series of push-pull systems comprised of phenothiazine dimers and strong electron acceptors, TCBD or DCNQ, have been newly synthesized and characterized by a suite of physicochemical methods. The significance of phenothiazine dimer in the push-pull systems in promoting wide-band optical capture into the near-IR region, and facilitating ultrafast photoinduced charge transfer as a function of donor-acceptor distance and solvent polarity is presented.

中文翻译：

强相互作用二苯噻嗪-TCBD 和二苯噻嗪-DCNQ 推挽三联体中的近红外分子内电荷转移

电荷转移。新合成了一系列由吩噻嗪二聚体和强电子受体 TCBD 或 DCNQ 组成的推挽系统，并通过一套物理化学方法对其进行了表征。介绍了推挽系统中吩噻嗪二聚体在促进宽带光学捕获进入近红外区域以及促进超快光诱导电荷转移作为供体-受体距离和溶剂极性函数的意义。

更新日期：2022-03-11

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