2-Bromo-3,3,3-Trifluoropropene: A Versatile Reagent for the Synthesis of Fluorinated Compounds,Advanced Synthesis & Catalysis

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2-Bromo-3,3,3-Trifluoropropene: A Versatile Reagent for the Synthesis of Fluorinated Compounds
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2022-03-11 , DOI: 10.1002/adsc.202200023
Qin Zhou ₁ , Yining Bao ₁ , Guobing Yan ₁

Affiliation

2-Bromo-3,3,3-trifluoropropene (BTP) represents a highly valuable synthon in synthetic chemistry, and has been widely used in organic synthesis, mainly including addition reactions, cross-coupling reactions, cycloaddition or cyclization reactions, S_N2’ reactions, and Stetter reactions for the construction of various fluorinated organic compounds. In this review, we systematically summarize these reactions; their mechanisms are also discussed.

中文翻译：

2-Bromo-3,3,3-Trifluoropropene：一种用于合成含氟化合物的多功能试剂

2-Bromo-3,3,3-trifluoropropene (BTP) 是合成化学中极具价值的合成子，在有机合成中有着广泛的应用，主要包括加成反应、交叉偶联反应、环加成或环化反应、S _N 2 ' 反应和 Stetter 反应，用于构建各种氟化有机化合物。在这篇综述中，我们系统地总结了这些反应；还讨论了它们的机制。

更新日期：2022-03-11

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