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Anti-perovskite materials for energy storage batteries
InfoMat ( IF 22.7 ) Pub Date : 2021-09-27 , DOI: 10.1002/inf2.12252
Zhi Deng ₁ , Dixing Ni ₁ , Diancheng Chen ₁ , Ying Bian ₁ , Shuai Li _{1,

2} , Zhaoxiang Wang _{3,

4} , Yusheng Zhao _{1,

2}

Affiliation

Anti-perovskites X₃BA, as the electrically inverted derivatives of perovskites ABX₃, have attracted tremendous attention for their good performances in multiple disciplines, especially in energy storage batteries. The Li/Na-rich antiperovskite (LiRAP/NaRAP) solid-state electrolytes (SSEs) typically show high ionic conductivities and high chemical/electrochemical stability toward the Li-metal anode, illustrating their great potential for applications in the Li-metal batteries (LMBs) using nonaqueous liquid electrolyte or all-solid-state electrolyte. The antiperovskites have been studied as artificial solid electrolyte interphase for Li-metal anode protection, film SSEs for thin-film batteries, and low melting temperature solid electrolyte enabling melt-infiltration for the manufacture of all-solid-state lithium batteries. Transition metal-doped LiRAPs as cathodes have demonstrated a high discharge specific capacity and good rate capability in the Li-ion batteries (LIBs). Additionally, the underlying scientific principles in antiperovskites with flexible structural features have also been extensively studied. In this review, we comprehensively summarize the development, structural design, ionic conductivity and ion transportation mechanism, chemical/electrochemical stability, and applications of some antiperovskite materials in energy storage batteries. The perspective for enhancing the performance of the antiperovskites is also provided as a guide for future development and applications in energy storage.

中文翻译：

储能电池用抗钙钛矿材料

反钙钛矿 X ₃ BA，作为钙钛矿 ABX _{3的电反转衍生物}，因其在多个学科中的良好表现而引起了极大的关注，尤其是在储能电池方面。富含锂/钠的反钙钛矿（LiRAP/NaRAP）固态电解质（SSE）通常表现出对锂金属负极的高离子电导率和高化学/电化学稳定性，说明它们在锂金属电池中的巨大应用潜力。 LMBs）使用非水液体电解质或全固态电解质。反钙钛矿已被研究作为用于锂金属负极保护的人造固体电解质界面、用于薄膜电池的薄膜 SSE，以及用于制造全固态锂电池的熔体渗透的低熔点固体电解质。过渡金属掺杂的LiRAPs作为正极在锂离子电池（LIBs）中表现出高放电比容量和良好的倍率性能。此外，具有灵活结构特征的反钙钛矿的基本科学原理也得到了广泛的研究。在这篇综述中，我们全面总结了一些反钙钛矿材料在储能电池中的发展、结构设计、离子电导率和离子传输机理、化学/电化学稳定性以及应用。还提供了提高抗钙钛矿性能的前景，作为未来发展和储能应用的指南。具有灵活结构特征的反钙钛矿的基本科学原理也得到了广泛的研究。在这篇综述中，我们全面总结了一些反钙钛矿材料在储能电池中的发展、结构设计、离子电导率和离子传输机理、化学/电化学稳定性以及应用。还提供了提高抗钙钛矿性能的前景，作为未来发展和储能应用的指南。具有灵活结构特征的反钙钛矿的基本科学原理也得到了广泛的研究。在这篇综述中，我们全面总结了一些反钙钛矿材料在储能电池中的发展、结构设计、离子电导率和离子传输机理、化学/电化学稳定性以及应用。还提供了提高抗钙钛矿性能的前景，作为未来发展和储能应用的指南。

更新日期：2021-09-27

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