Modification of Nitrate Ion Enables Stable Solid Electrolyte Interphase in Lithium Metal Batteries,Angewandte Chemie International Edition

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Modification of Nitrate Ion Enables Stable Solid Electrolyte Interphase in Lithium Metal Batteries
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-03-01 , DOI: 10.1002/anie.202201406
Li-Peng Hou ₁ , Nan Yao ₁ , Jin Xie ₁ , Peng Shi ₁ , Shu-Yu Sun ₁ , Cheng-Bin Jin ₁ , Cheng-Meng Chen ₂ , Quan-Bing Liu ₃ , Bo-Quan Li ₄ , Xue-Qiang Zhang _{4,

5} , Qiang Zhang _{1,

5}

Affiliation

The modification of NO₃⁻ is achieved by connecting NO₃⁻ to an ether-based moiety. The broken resonance structure of −NO₃ improves its reducibility compared with NO₃⁻. The decomposition of −NO₃ forms a LiN_xO_y-rich solid electrolyte interphase (SEI) and induces uniform Li deposition.

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