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A Crystalline Partially Fluorinated Triazine Covalent Organic Framework for Efficient Photosynthesis of Hydrogen Peroxide
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-02-28 , DOI: 10.1002/anie.202202328
Haozhen Wang 1 , Chao Yang 2 , Fangshuai Chen 1 , Gengfeng Zheng 2 , Qing Han 1
Affiliation  

A crystalline, partially fluorinated triazine covalent organic framework (COF) was constructed with broad visible-light responsiveness, improved charge separation and transfer, and enhanced O2 affinity. The COF exhibited attractive photocatalytic activity, selectivity, and stability for H2O2 production under visible-light irradiation, and with higher activity than previously reported nonmetal COF-based photocatalysts.

中文翻译:

用于高效光合作用过氧化氢的结晶部分氟化三嗪共价有机骨架

构建了一种结晶的、部分氟化的三嗪共价有机骨架(COF),具有广泛的可见光响应性、改进的电荷分离和转移以及增强的 O 2亲和力。COF在可见光照射下对H 2 O 2的产生表现出有吸引力的光催化活性、选择性和稳定性,并且比之前报道的非金属COF基光催化剂具有更高的活性。
更新日期:2022-02-28
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