Nanographene with Multiple Embedded Heptagons: Cascade Radical Photocyclization,Angewandte Chemie International Edition

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Nanographene with Multiple Embedded Heptagons: Cascade Radical Photocyclization
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-02-22 , DOI: 10.1002/anie.202116955
Zhen-Lin Qiu ₁ , Xuan-Wen Chen ₁ , Yu-Dong Huang ₁ , Rong-Jing Wei ₁ , Ke-Shan Chu ₁ , Xin-Jing Zhao ₁ , Yuan-Zhi Tan ₁

Affiliation

Photo-induced radical cyclization was used in the synthesis of nanocarbons with embedded heptagons, providing a new approach towards nanocarbons with novel topologies. The nanographene reported herein bears six heptagons, representing the nanocarbon containing the largest number of heptagons by organic synthesis reported to date. The embedded heptagons distort the graphene core into a Monkey-saddle-shaped conformation.

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