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Pyromellitic Diimide-Extended Pillar[6]arene: Synthesis, Structure, and Its Complexation with Polycyclic Aromatic Hydrocarbons
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2022-02-16 , DOI: 10.1021/acs.joc.1c03096 Fei Zeng 1 , Lu Cheng 2 , Guang-Chuan Ou 1 , Lin-Li Tang 1 , Man-Hua Ding 1
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2022-02-16 , DOI: 10.1021/acs.joc.1c03096 Fei Zeng 1 , Lu Cheng 2 , Guang-Chuan Ou 1 , Lin-Li Tang 1 , Man-Hua Ding 1
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A novel pyromellitic diimide-extended pillar[6]arene was synthesized in two steps with moderate yield for the first time. It showed a symmetrical stretched hexagon structure and could form 1:2 complexes with polycyclic aromatic hydrocarbons in solution. Interestingly, a linear supramolecular array between complex 1@G42 and pyrene through π···π stacking interactions was also observed in the solid state.
中文翻译：
均苯四酸二酰亚胺延伸柱[6]芳烃：合成、结构及其与多环芳烃的络合
首次分两步合成了一种新型均苯四酸二亚胺延伸柱[6]芳烃，产率适中。呈对称拉伸六边形结构，在溶液中能与多环芳烃形成1:2的络合物。有趣的是，复合物1@G4 2和芘之间通过π···π 堆积相互作用在固态下也观察到了线性超分子阵列。
更新日期：2022-02-16
中文翻译：
均苯四酸二酰亚胺延伸柱[6]芳烃：合成、结构及其与多环芳烃的络合
首次分两步合成了一种新型均苯四酸二亚胺延伸柱[6]芳烃，产率适中。呈对称拉伸六边形结构，在溶液中能与多环芳烃形成1:2的络合物。有趣的是，复合物1@G4 2和芘之间通过π···π 堆积相互作用在固态下也观察到了线性超分子阵列。
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