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Dibenzodiazapyracylenes: Doubly N-Doped Cyclopenta-Fused Polycyclic Molecules That Exhibit High Carrier Mobility
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-02-04 , DOI: 10.1002/anie.202200341
Yuki Morimoto 1 , Yun Hee Koo 2 , Kazuya Otsubo 1 , Hidetsugu Kitakado 1 , Shu Seki 2 , Atsuhiro Osuka 1 , Takayuki Tanaka 1, 2
Affiliation  

A novel nitrogen-doped CP-PAH, dibenzodiazapyracylene, was successfully synthesized and characterized. The aromatic and antiaromatic resonance hybrid characters have been verified by comparing their 1H NMR spectra to those of reference molecules. Their condensed packing structures in the solid state allowed for the effective hole transporting.

中文翻译:

二苯并二氮杂吡咯:具有高载流子迁移率的双 N 掺杂环戊稠合多环分子

成功合成并表征了一种新型的氮掺杂 CP-PAH 二苯并二氮杂萘。通过将它们的1 H NMR 光谱与参考分子的光谱进行比较,验证了芳香族和反芳香族共振杂化特征。它们在固态下的凝聚填充结构允许有效的空穴传输。
更新日期:2022-02-04
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