Journal of Chemical Sciences ( IF 1.7 ) Pub Date : 2022-01-25 , DOI: 10.1007/s12039-021-02012-2 Mohammad El-Khateeb 1 , Alaa Al-Momani 1 , Pilar Garcia-Orduna 2 , Fernando J Lahoz 2
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In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)2SSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)2SeSO2CH=CHPh (2) featuring styrene moiety. 1 and 2 are obtained by electrophilic attack of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) on the sulfur atom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized by elemental analyses, IR, 1H-, 13C{1H}-NMR, UV–Vis spectroscopy and the structure of 2 is determined by X-ray crystallography.
Graphical abstract
In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)2SSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)2SeSO2CH=CHPh (2) featuring styrene moiety. 1 and 2 are obtained by electrophilic attack of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) on the sulfur atom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized by elemental analyses, IR, 1H-, 13C{1H}-NMR, UV–Vis spectroscopy and the structure of 2 is determined by X-ray crystallography..
中文翻译：
环戊二烯铁二羰基苯乙烯硫族磺酸盐：CpFe(CO)2SeSO2CH=CHPh的合成和结构
在这篇文章中，我们报道了铁硫代磺酸根络合物 CpFe(CO) 2 SSO 2 CH=CHPh ( 1 ) 及其具有苯乙烯部分的硒代磺酸根类似物 CpFe(CO) 2 SeSO 2 CH=CHPh ( 2 ) 的制备。1和2是通过(μ-E x )[CpFe(CO) 2 ] 2 (E = S; x = 2-4, E = Se; x = 1)对苯乙烯磺酰氯的硫原子进行亲电攻击而获得的ClSO 2 CH=CHPh。新化合物1和2已通过元素分析、IR、1 H-、13进行了表征C{ 1 H}-NMR、UV-Vis 光谱和2的结构由 X 射线晶体学确定。
图形概要
在这篇文章中，我们报道了铁硫代磺酸根络合物 CpFe(CO) 2 SSO 2 CH=CHPh ( 1 ) 及其具有苯乙烯部分的硒代磺酸根类似物 CpFe(CO) 2 SeSO 2 CH=CHPh ( 2 ) 的制备。1和2是通过 (μ-Ex)[CpFe(CO) 2 ] 2 (E = S; x = 2–4, E = Se; x = 1) 对苯乙烯磺酰氯 ClSO 的硫原子的亲电攻击获得的2 CH=CHPh。新化合物1和2已通过元素分析、IR、1 H-、13 C{ 1进行了表征H}-NMR、UV-Vis 光谱和2的结构由 X 射线晶体学确定。
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