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Three-Dimensional Triptycene-Functionalized Covalent Organic Frameworks with hea Net for Hydrogen Adsorption
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-01-24 , DOI: 10.1002/anie.202117101
Chengyang Yu 1 , Hui Li 1 , Yujie Wang 1 , Jinqun Suo 1 , Xinyu Guan 1 , Rui Wang 1 , Valentin Valtchev 2, 3 , Yushan Yan 4 , Shilun Qiu 1 , Qianrong Fang 1
Affiliation  

3D COFs with a non-interpenetrated hea net, JUC-596 and JUC-597, are designed and successfully synthesized for the first time. Remarkably, JUC-596 exhibits an exceptional performance in H2 adsorption up to 305 cm3 g−1 (or 2.72 wt%) at 77 K and 1 bar, which is higher than previous benchmarks from porous organic polymers reported so far.

中文翻译:

具有热网的三维三蝶烯功能化共价有机骨架用于氢吸附

首次设计并成功合成了具有非互穿热网 JUC-596 和 JUC-597 的 3D COF 值得注意的是,JUC-596 在 77 K 和 1 bar 下表现出优异的 H 2吸附性能,高达 305 cm 3  g -1(或 2.72 wt%),这高于迄今为止报道的多孔有机聚合物的先前基准。
更新日期:2022-01-24
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